The class isn't the best place to do chem so the lab is where I go
Me and my friends at the bench doing reflux
Turn the heat high and then turn it low
nucleophile starts substitution with carbon
And they'll give SN2 a chance now Break the bond, stop, donate electrons And then bromine starts to leave, and I'm reacting like
Nucleophile, I want your bond My sigma star was made for somebody like you Come on now, donate to me
I'm hybridized to sp3. Hey, nuc(leophile), bimolecular
Grab that carbon, invert my stereochem Come on now, stereochem Come, come on now, stereochem
I'm in love with stability The nucleophile donates e-
Although my LG will leave too Nucleophile to the electrophile
This is concerted for SN2 We're surrounded by aprotic solvent So there's a weaker solvent shell
nucleophile to the electrophile s-p-s-p-s-p-3
I'm in love with tetrahedral geometry s—p—s—p—s—p—3
I'm in love with tetrahedral geometry s—p—s—p—s—p—3
I'm in love with tetrahedral geometry Every day bonding with new molecules I'm in love with stability
Dale and the best place to do come so the lab is where I go, ooh
Me and my friends at the bench doin reflux turn the heat high on the Turner low
Sometimes sterically in it or your nuke is a strong base like when you're followed by TV you
So instead of the fact side you attack any cleaner, and you'll go with you to acting like you've got one
bulb on my
MOS means for spotty like you come on now limite teenage all hybrid ice to SP to a
second order rate laws grabbed our carbon
Come on now Cara lady come come on now Cara lady
I'm in love with the bear lady, and if we file donate see my algae is leave into
base to the proton
Concerted 42 were surrounded by protic solvent
Base to the proton
I'm in love with planar geometry
In love was planar geometry
I'm in love with planar geometry
I'm in love with the bay lady come on with my electrons, baby
Come on bond electrons come on come on bond electrons come on come on bond electrons come on
Come on bond electrons come on come on
Electrons come on come on bond electrons come on come on bond electrons come on
I'm in love with stability
Which happens with the localized D. Although my allergies leave in to be filed in electrophile
Considered it for us into an e2 we're surrounded by TMS so every day do something new
nucleophiles and electrophiles
be Espie Espie Espie
I'm in love with geometry Espie Espie, Espie. I'm in love with the geometry
BSP BSP am in love with organic chemistry every day bonding with new
Molecules I'm in love with Mandy
For more infomation >> Yale Organic Chemistry - The Geometry of You - Duration: 4:05.-------------------------------------------
How YOU can help preserve the Avro Lancaster! - Duration: 1:51.
The Avro Lancaster was one of the largest and most important British and Canadian aircraft
to fly during the Second World War.
With a payload of up to 22,000 pounds, a range of 2,500 miles and a cruising
speed of 210 miles per hour, this aircraft played a major
role in the allied bombing command in the European theater of the conflict.
A total of 7,377 Lancaster aircraft were produced, including many that were produced in Canada.
However as of today only 16 of them have survived, 8 of them in Canada: 1 in Nova Scotia, 2 in
Alberta and 5 of them in the Province of Ontario.
One of the five Lancasters in Ontario is named FM104 and right now it is sitting on a storage
facility in a partially restored condition.
This artefact of Canadian history is owned by the city of Toronto and the mayor's office
has already put a request for it to be given away since city is unable to find a suitable
place for the aircraft.
In light of this the Canadian Museum of Flight, located in Langley, British Columbia would
like to acquire this Lancaster in order to preserve it and have it on display for the
millions of Canadians that live in the west coast.
The museum has already sent an official proposal to the city of Toronto with our offer to acquire
and restore the Lancaster FM104, however we would also like your support in order to preserve this
aircraft, both a symbol of freedom and as well tribute to all Canadians and allies who
served during the war.
If you agree with the plan of the Canadian Museum of Flight to preserve the Avro Lancaster,
please sign our petition in the link attached to this video and also do not forget to tell
all your friends about the petition so that we can preserve this important piece of Canadian
history and have it available for the Canadians who live in the west coast, because at the
end of the day this is part of our common history and British Columbia
would like to do its part in preserving it.
-------------------------------------------
Colleen Lopez Apron, Oven Mitt and Pot Holder Set - Duration: 10:20.
For more infomation >> Colleen Lopez Apron, Oven Mitt and Pot Holder Set - Duration: 10:20. -------------------------------------------
BIG Democrat Who Called Hillary Out To Her Face Just Became Her Most Recent ...| Global News Today - Duration: 4:59.
BIG Democrat Who Called Hillary Out To Her Face Just Became Her Most Recent Victim Overnight.
For years, the American people have noticed a disturbing trend of mysterious deaths connected
to the Clintons.
It appears that when anyone crosses the Clinton family, they end up six feet under or become
the victims of a character assassination that leaves them penniless and alone.
While the mainstream media and law enforcement agencies continue to ignore the Clinton connection,
victims continue to pile up with no end in sight.
Just over this past year, Hillary Clinton has been implicated in several strange deaths
stemming back to DNC staffer Seth Rich.
Then there was the recent death of longtime Clinton investigator Peter W. Smith followed
by Klaus Eberwein, a former Haitian government official who was just about to blow the whistle
on the Clinton Foundation.
Of course there are many more victims that have fallen prey to the Clintons, but the
pattern is all the same.
If you cross the Clintons or try to expose them for the crimes they committed you will
meet your demise, and it doesn't matter who you are either.
Now another victim of Hillary Clinton's wrath was just destroyed publicly who also
happened to be a longtime supporter, and it proves that no one is safe from her tentacles.
Over the last several weeks, there has been a flurry of sexual allegations against politicians,
celebrities, and high-powered executives.
Almost every day another person is fingered as a "pervert" and yesterday was no exception
as the Today Show's Matt Lauer was named as the latest perpetrator of these crimes.
On Monday night, a detailed complaint was sent to NBC that contained a list of actions
inflicted on several victims by the hands of Lauer.
The allegations against the TODAY anchor go back over a decade, and each new report is
more damning than the last.
Though what is suspicious about these reports is the timing of them and has many people
wondering if there is an alternative motive of revenge.
As you know, Hillary Clinton released a book titled, "What Happened" that was a colossal
failure, but in this rubbish was a clue.
Clinton described in the book how she was angered that Lauer questioned her about her
private server during an interview last year.
NBC hosted a "Commander-in-Chief Forum" aboard the USS Intrepid on Sept. 6, 2016,
and the event was supposed to focus on the candidates' stances on foreign policy.
But during the interview, Lauer, the longtime host of the "Today" show, questioned Clinton
on the email scandal.
Here is more from Washington Examiner on that interview:
"Now I was ticked off," Clinton wrote in her forthcoming book "What Happened"
according to reports.
"NBC knew exactly what it was doing here.
The network was treating this like an episode of 'The Apprentice,' in which Trump stars
and ratings soar.
Lauer had turned what should have been a serious discussion into a pointless ambush.
What a waste of time."
Clinton said she found the interview with Lauer "disappointing but predictable."
"I can't say I didn't fantasize about shaking some sense into Lauer while I was
out there," she said.
Then-candidate Donald Trump took the stage after Clinton's 30-minute interview, and
the Democratic presidential nominee said Lauer gave her Republican opponent a "soft-pedal"
interview.
"I was almost physically sick," Clinton said.
Now no one is saying that Lauer is innocent of these horrific sexual attacks against these
victims, but you have to admit the timing is somewhat suspicious.
Let us be real here, Hillary is not about to allow someone like Lauer embarrass her
publicly on national television and let them get away with it.
Also, the obvious question is how did this abuse go on for so long undetected?
Whether or not Lauer did it someone knew about it and helped cover it up which is why these
sexual perverts have gotten away with it for so long.
And, Hillary Clinton knows a thing or two about covering sexual perversion up since
she is married to the biggest deviant in the country, her husband Bill Clinton.
No one can tell me that people in the NBC offices were not aware of Lauer's sexual
predilections.
People talk and you can be sure someone reported this to the Clintons and she tucked it away
for a rainy day when she would need to lash back.
The moral of this story is that when you are dealing with the Clintons no one is safe from
their reach and if they want to destroy you they will.
Hopefully, President Trump will keep his promise and investigate Hillary for all her crimes
past and present so she can receive a taste of her own medicine sooner than later.
-------------------------------------------
[ENG SUB] A Pink Eunji - Only You [cover Huh Gak] - Duration: 4:49.
For more infomation >> [ENG SUB] A Pink Eunji - Only You [cover Huh Gak] - Duration: 4:49. -------------------------------------------
Last Moment- Yousei Teikoku [Captions] - Duration: 4:16.
Be in the grip of Death! Jesus!
Mercy killing! Last moment!
Be in the grip of Death! Jesus!
Mercy killing! Last moment!
Be in the grip of Death! Jesus!
Mercy killing! Last moment!
Be in the grip of Death! Jesus!
Mercy killing! Last moment!
Be in the grip of Death! Jesus!
Mercy killing! Last moment!
Be in the grip of Death! Jesus!
Mercy killing! Last moment!
Be in the grip of Death! Jesus!
Mercy killing! Last moment!
Be in the grip of Death! Jesus!
Mercy killing! Last moment!
A white light shines in,
And I repeat the same awakening
The red light announces the end,
Will tomorrow come...?
Be in the grip of Death! Jesus!
Mercy killing! Last moment!
Be in the grip of Death! Jesus!
Mercy killing! Last moment!
Why were we given life?
What were we born to do?
Offering prayers to god,
But our wishes will never reach him
Stretching out my black wings,
I get lost in the darkness, don't touch me
Not even telling you the pain of this farewell
Be in the grip of Death! Jesus!
Mercy killing! Last moment!
Be in the grip of Death! Jesus!
Mercy killing! Last moment!
It would be hypocritical of me,
To ask you to forget me
When you gave me a memory,
I don't want to forget
What should I wish for...?
The next time I wake,
I might be somewhere where you are not
Until the day I return to the sky,
Let me hear your voice
Raising your hoarse voice,
You called to me to not go
I wonder how long,
I will be able to touch you?
Is this the last day?
I still want to be inside of your heart!
Will even these feelings disappear...
-------------------------------------------
Trident Leasing - Gin Joint - Duration: 0:57.
- Once I decided that I wanted to
establish a distillery,
I went across to Kentucky, in America,
and graduated from Moonshine University.
(upbeat music)
- My name's Liz Beech,
and the business is, 'Of All The Gin Joints'.
- Her dream was to have, and manufacture, her own gin.
And we were able to put the funding together for her.
- There's was a lot of stumbling blocks, I suppose.
But Peter persevered with it,
and eventually, we were able to get it through.
(upbeat music)
I certainly recommend Peter,
whatever project it is,
however small or large, or unusual.
Yeah, he'll certainly do his best to help you out.
- If I can help you with anything,
if you wanna learn more,
advice is free,
please call Peter Nicholls--
- And Max Hamond on 1300 883 718.
- And Max Hamond, the new member of the team
at Trident Leasing.
-------------------------------------------
Black Squad - The Way to Be a Pro - Duration: 11:48.
For more infomation >> Black Squad - The Way to Be a Pro - Duration: 11:48. -------------------------------------------
Butterfly swimming without getting tired (5 Stage techniques for beginners) - Duration: 5:42.
this is a guide to help you swim butterfly without getting tired.
It consists of 5 phases.
I'm not saying that you will watch this video and you'll immediately go to the pool
and swim hundreds of yards without breaking a sweat.
No no, on this video I will show you a series of progressive exercises that you can do to
that if done well and often will help you create muscle memory for a smooth easy butterfly.
Along with muscles memory you will develop endurance that is basic for all things swimming.
I did a video a while ago about exercises for core muscles for dolphin kick.
If you haven't seen it I recommend watching it since it will help you with butterfly too.
If you have core strength then swimming butterfly is much easier.
If you do have some core strength and you still can't swim butterfly without getting
extremely tired then chances are your timing is off.
To perfect your technique let's begin with some shoulder warm up.
Remember that this is the hardest stroke on your shoulders so you need to warm them up
well before swimming.
Now lets do butterfly kick to warm up the core and leg muscles.
This exercise is quite challenging but it helps you focus on a quick breath and using
your legs properly.
So put your hands to your sides and dolphin kick your way across the pool.
Remember to use your chest, your hips and then your legs.
Now this one is a bit easier.
Try doing dolphin kick on your back while holding a kick board on your hands and keeping
it above the surface.
This will help you keep the arms in place.
Doing kick like this with a board, will help you stretch your shoulders to the range of
movement you will need to swim butterfly without getting tired.
Try exaggerating the movement of the chest and leaving the shoulders on the surface with
the board.
This is a little more technical but it will help you reduce unnecessary efforts while
you swim.
Kick with your arms straight in front and pull your body Forward with your head coming
out of the water just barely to take a breathe.
Then recover your hands underwater like so and start again.
Remember that our goal is to swim smoothly by identifying and correcting all the ineffective
swimming techniques.
In butterfly the arms should pull your body forward and not up like many of us do.
This is the best way of correcting that.
I recommend doing this exercise for about 4 x 25s every time you plan on swimming butterfly.
Now if you want more power in your pull, this exercise is helpful.
It helps if you swim in a deeper pool but just try not touching the floor.
Get your arms on this position.
Your head should be in front of your shoulder line.
If you are not quite there yet it means that you need more shoulder flexibility.
We have a video about shoulder flexibility btw.
Now pull yourself out of the water like this and repeat.
This emulates your stroke but with gravity forcing you to do a bit more effort.
The next stage is to do butterfly with one arm.
This is much easier than doing butterfly with both arms but you need to focus on the position
of the head and hips.
These two parts, the head and the hips will guide the undulating movement of the body.
Once you dominate this part you can do the same exercise but with your resting arm down
by your side like this.
This is slightly harder because you don't have the leverage of the other arms to get
your head out, so this will help you to use your other arm more effectively.
Once you can do around a 100 meters of catching arm butterfly without getting really tired
you can move on to the next phase!
ON this phase your mission is to do this exercise without getting tired.
Do one arm butterfly then the other, then do one or two full strokes.
This exercise is good because it helps you recover your arms before the next full stroke
cycle.
It also helps with your coordination and concentration.
Once you perfect this stroke exercise to the point where you can swim relaxed but smooth
and at a constant speed you can do the next phase of exercises.
Phase 5 Now you can do exercises all day long but
at the end of the day there is no escaping the real thing.
Swimming full butterfly is what will help you the most.
If your shoulders are strong, your core is tight and you have good ankle flexibility,
now that you have worked on your technique, you are all set to swim a smooth and fast
butterfly.
Just remember to warm up properly and stretch afterwards.
I hope you use this guide and up your butterfly game to the next level.
If you like what we do, one of the best way to support us, besides watching our videos,
is visiting our website.
We have swim caps and more swimming content there.
Thanks for watching!
See you next time!
Swim fast!
-------------------------------------------
Don't Buy An Around The World Ticket - Duration: 4:13.
so my advice in this video is to not buy around the world ticket I still hear
people talking about round-the-world tickets and it's not worth it you don't
actually really save that much nowadays but it just spoils your plans if you
haven't really done a lot of traveling before you don't know how it works but
you get somewhere you talk to people and they talk about places they've been and
they get excited about it you get excited about it and you want to go
there as well and that's exactly what happened to me originally I was looking
at an around the world ticket because I started traveling in 1990 and it was a
lot cheaper at that time but I joined up with three other people and they had
bought just four tickets they bought one to India then
from Nepal to Hong Kong from Hong Kong to the Philippines and Philippines
Thailand so they bought these four tickets so I did the same as them and
we stayed together two weeks that was the plan and then we went off on her own
but even after that I didn't even want to use the second one I was in Nepal
trekking and met a guy who was planning to go to Tibet and it just sounded great
he'd looked into it and talked to people about it and it sounded great but I
couldn't go because I had a ticket to Hong Kong so I just arranged to meet him
in a month's time in Thailand and then we planned to go to
Vietnam and Cambodia because at that time it was quite difficult to travel
there and it just sounded like an adventurer so I had to do it really
quickly go to hong kong quick look around philippines quick look back to
thailand to meet him in a month's time and really that's why i would say just
don't book a world ticket your plans change or your dates change and you meet people
who are doing other things and you just get into this excitement and you can't
do it if you if you've already got that flight booked even if you change the
date it just it restricts you so much now around asia that it's really easy to
get one-way tickets and I use Skyscanner.net and it can compare
the different flights and I just go somewhere and then when I want to go
somewhere else I just booked another ticket find a cheap one online and works
pretty easy the only problem is if you're coming from Europe then quite
often they won't let you get on the plane with a one-way ticket and that's
because they'll get a fine if you get refused entry into a country
then they'll get a fine I think it's three thousand dollars so quite often
they won't let you go on a one-way ticket but you could just buy a cheap
ticket from the country you're going to to another country you can buy like in
Thailand you could buy a cheap ticket to another country for about $20 or $30 so
you can do it that way or if you get the visa for the country it's okay it's just
if you're going on a one-way ticket with no visa that's when you get the problem
so that's what I recommend and I've been doing this 27 years I just find it's a
great way you've just got so much freedom
this year I've already been to Vietnam Cambodia and Malaysia
I just love it all so that's my advice if you found this useful please give it
a thumbs up my channel is all about traveling and working while you're
traveling or working online as I say I left 27 years ago in 1990 and
I've just got this experience of doing it and I want to give you that advice I
also want to give you some encouragement to do the same sort of thing yourself so
if they interest you please subscribe to my channel if you've got any questions
about traveling around Asia or working online please put them in the comments
below and if you've got experience yourself then please let others know so
also put that in the comments so thanks for watching this video and I'll see you
in the next one
-------------------------------------------
Armando Giglia, WA Secondary Principal of the Year - Duration: 1:25.
I think every principal makes a difference and wants to make a
difference otherwise they wouldn't be there. It's not an easy position
and it's lonely at the top at times but you build a team around you and if
you build the team around you it'll happen. I'm just passionate about public
school education and I just hope that that keeps coming through to to people
wherever and whenever I am in their presence I just think that education is
the answer to bridging a gap with people and if I can be in any way part of that
and then I want to be I just think that our kids deserve everything that could
come their way and I think I've put together a staff that can do that for me.
I'm pretty sure that they'll be happy, I hope they are, that as a school
we've been recognised it's not to me about me it's about the people I've got
working around me. It's that team. We really believe that
together everyone achieves more that's why we keep talking about team at Butler.
I've had the privilege of getting those people together over the past few years
and I think they're making a difference in the local community and I hope the
local community really does appreciate it. I think they do.
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